Studies of Flerovium and Element 115 Homologs with Macrocyclic Extractants
نویسندگان
چکیده
........................................................................................................................... III ACKNOWLEDGEMENTS ........................................................................................................ VI LIST OF FIGURES ................................................................................................................. XIII LIST OF TABLES ................................................................................................................. XVII LIST OF EQUATIONS ......................................................................................................... XVIII CHAPTER 1: INTRODUCTION ..................................................................................................1 1.1 Stability of the transactinides ...........................................................................................4 1.2 Production of the transactinides .......................................................................................6 1.2.1 Element 114, Flerovium ..................................................................................................... 9 1.2.2 Element 115 ...................................................................................................................... 11 1.3 Chemistry of the transactinides ...................................................................................... 14 1.4 Predicted properties of Flerovium ................................................................................... 20 1.5 Predicted properties of Element 115 ............................................................................... 23 1.6 Chemical properties of group 12, 13, 14 and 15 ............................................................... 24 1.6.1 Group 12 chemical properties, the homologs of Cn and pseudo-homolog of Fl ........... 24 1.6.2 Group 13 chemical properties, the homologs of element 113 and pseudo-homologs of element 115 ............................................................................................................................... 25 1.6.3 Group 14 chemical properties, the direct homologs of Fl .............................................. 27 1.6.4 Group 15 chemical properties, the direct homologs of element 115 ............................ 30 1.7 Macrocycles ................................................................................................................... 33 1.7.1 Crown ethers .................................................................................................................... 34 1.7.2 Thiacrown ethers ............................................................................................................. 36 1.8 Dissertation overview ..................................................................................................... 37 1.9 Project Goals .................................................................................................................. 38 CHAPTER 2: BACKGROUND .................................................................................................. 39
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